PMSEvidence & Dosage

Top studies on PMS

Ranked by influential-citation count and publication year.

1. 01

   Tailoring d-band center of high-valent metal-oxo species for pollutant removal via complete polymerization.

   Nature communications·2024200 influential citations

   Polymerization-driven removal of pollutants in advanced oxidation processes (AOPs) offers a sustainable way for the simultaneous achievement of contamination abatement and resource recovery, supporting a low-carbon water purification…

2. 02

   Fenton-like activity and pathway modulation via single-atom sites and pollutants comediates the electron transfer process.

   Proceedings of the National Academy of Sciences of the United States of America·2024200 influential citations

   The studies on the origin of versatile oxidation pathways toward targeted pollutants in the single-atom catalysts (SACs)/peroxymonosulfate (PMS) systems were always associated with the coordination structures rather than the perspective of…

3. 03

   Unveiling the Origins of Selective Oxidation in Single-Atom Catalysis via Co-N 4 -C Intensified Radical and Nonradical Pathways.

   Environmental science & technology·2022142 influential citations

   Single-atom catalysts (SACs)-based peroxymonosulfate (PMS) systems are highly selective to the type of organic pollutants while the mechanisms remain ambiguous. In this work, we carried out experimental and theoretical investigations to…

4. 04

   Coordination engineering of heterogeneous high-valent Fe(IV)-oxo for safe removal of pollutants via powerful Fenton-like reactions.

   Nature communications·2024125 influential citations

   Coordination engineering of high-valent Fe(IV)-oxo (Fe^IV=O) is expected to break the activity-selectivity trade-off of traditional reactive oxygen species, while attempts to regulate the oxidation behaviors of heterogeneous…

5. 05

   Trace Cupric Species Triggered Decomposition of Peroxymonosulfate and Degradation of Organic Pollutants: Cu(III) Being the Primary and Selective Intermediate Oxidant.

   Environmental science & technology·2020118 influential citations

   Activation of persulfates to degrade refractory organic pollutants is currently a hot topic of advanced oxidation. Developing simple and effective activation approaches is crucial for the practical application of persulfates. We report in…

6. 06

   Single-atom Mo-Co catalyst with low biotoxicity for sustainable degradation of high-ionization-potential organic pollutants.

   Proceedings of the National Academy of Sciences of the United States of America·202391 influential citations

   Single-atom catalysts (SACs) are a promising area in environmental catalysis. We report on a bimetallic Co–Mo SAC that shows excellent performance in activating peroxymonosulfate (PMS) for sustainable degradation of organic pollutants with…

7. 07

   Ultrahigh Peroxymonosulfate Utilization Efficiency over CuO Nanosheets via Heterogeneous Cu(III) Formation and Preferential Electron Transfer during Degradation of Phenols.

   Environmental science & technology·202285 influential citations

   In persulfate activation by copper-based catalysts, high-valent copper (Cu(III)) is an overlooked reactive intermediate that contributes to efficient persulfate utilization and organic pollutant removal. However, the mechanisms underlying…

8. 08

   Dissolved organic matter promotes photocatalytic degradation of refractory organic pollutants in water by forming hydrogen bonding with photocatalyst.

   Water research·202373 influential citations

   Removing refractory organic pollutants in real water using photocatalysis is a great challenge because coexisting dissolved organic matter (DOM) can quench photogenerated holes and thus prevent generation of reactive oxygen species (ROS).…

9. 09

   Facilitating Redox Cycles of Copper Species by Pollutants in Peroxymonosulfate Activation.

   Environmental science & technology·202260 influential citations

   The redox behavior of metal active sites determines the rate of heterogeneous catalysis in peroxymonosulfate activation. Previous reports focused on the construction of catalysts for accelerating interfacial electron transfer. In this…

10. 10

    Novel g-C3N4-x nanosheets/MoS2 binary photocatalyst achieves stable construction of Z-scheme heterojunction via nitrogen defect induced 2D interface C-S bonds for efficient PMS activation and degradation of sulfamethoxazole

    Environmental Research·20254 influential citations

    The inadequate utilization of visible light and the ineffective separation of electrons and holes in bulk-phase g-C₃N₄ renders its coupling with persulfate (PMS) inefficient in oxidative degradation of refractory…